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2024(top)



• Sawant, K. J., Zeng, Z., & Greeley, J. P., Origin of Stability and Activity Enhancements in Pt-based Oxygen Reduction Reaction Catalysts via Defect-Mediated Dopant Adsorption., Angewandte Chemie International Edition, 63(5), e202312747, (2024).
• Santiago-Colón, Á. N., & Gounder, R., Structural changes to molybdenum and Brønsted acid sites in MFI zeolites during methane dehydroaromatization reaction-regeneration cycles., Journal of Catalysis, 430, 115335, (2024).
• Ezenwa, S., Hopping, G. M., Sauer, E. D., Scott, T., Mack, S., & Gounder, R., Quantification of extracrystalline acid sites in MFI zeolites after post-synthetic passivation treatments using mesitylene benzylation kinetics., Reaction Chemistry & Engineering, (2024).
• Talpade, A. D., Canning, G., Zhuchen, J., Arvay, J., Watt, J., Miller, J. T., Datye, A., & Ribeiro, F. H., Catalytic reactivity of Pt sites for non-oxidative coupling of methane (NOCM)., Chemical Engineering Journal, 481, 148675, (2024).
• Smith, J. G., Sawant, K. J., Zeng, Z., Eldred, T. B., Wu, J., Greeley, J. P., & Gao, W., Disproportionation chemistry in K2PtCl4 visualized at atomic resolution using scanning transmission electron microscopy., Science Advances 10(6), 175., (2024).



2023(top)



• Morankar, A., Deshpande, S., Zeng, Z., Atanassov, P., & Greeley, J., A first principles analysis of potential-dependent structural evolution of active sites in Fe-N-C catalysts., Proceedings of the National Academy of Sciences of the United States of America, 120(49), e2308458120 (2023).
• Velinkar, K. K., Gunten, A. von, Greeley, J., & Nikolla, E., Influence of the Mechanism of Discharge Product Formation on the Electrochemical Performance and Cyclability of Aprotic Na-O2 Batteries., ACS Energy Letters, 8(11), 4555–4562 (2023).
• Arinaga, A. M., Biswas, A., Zhang, X., Greeley, J., & Marks, T. J., Origin of Rate and Selectivity Trends and Exceptional Yield in Sulfur-Oxidative Propane Dehydrogenation Over Supported Vanadium Catalysts., ACS Catalysis, 13(20), 13395–13413 (2023).
• Zeng, Z., Dionigi, F., Zhu, J., Liang, J., Li, W.-X., Strasser, P., & Greeley, J., Fundamental Insights into Reaction Centers and Catalytic Mechanisms of Ni- and Co-Based Layered Oxyhydroxides for the Oxygen Evolution Reaction., ECS Meeting Abstracts, MA2023-01(36), 1965 (2023).
• Dionigi, F., Zeng, Z., Zhu, J., Merzdorf, T., Klingenhof, M., Buchheister, P. W., Li, W.-X., Greeley, J., & Strasser, P., Structural Transformations in Ni (Oxy)Hydroxide Host Structures Under Operating Conditions for Oxygen Evolution Electrocatalysts., ECS Meeting Abstracts, MA2023-01(36), 2062. (2023).
• Von Gunten, A., Velinkar, K., Nikolla, E., & Greeley, J., Elucidation of Parasitic Reaction Mechanisms at Interfaces in Na-O2 Batteries. , Chemistry of Materials, 35(15), 5945–5952. (2023).
• Bukowski, B. C., Purdy, S. C., Wegener, E. C., Wu, Z., Kropf, A. J., Zhang, G., Miller, J. T., & Greeley, J., Intermetallic alloy structure–activity descriptors derived from inelastic X-ray scattering. , Physical Chemistry Chemical Physics, 25(16), 11216–11226. (2023).
• Chun, H. J., Morankar, A., Zeng, Z., & Greeley, J., Solvation Enthalpy Determination for Aqueous-Phase Reaction Adsorbates Using Ab Initio Molecular Dynamics-Based Structure Sampling., Journal of Physical Chemistry C, 128, 1621–1632, (2023).
• Bickel, E. E.; McGinness, H.; Zamiechowski, N.; Gounder, Synthetic Methods to Vary Crystallite Properties of TON Zeolites and Their Consequences for Brønsted-Acid Catalyzed Propene Oligomerization., Journal of Catalysis, 2023, 426, 189–199
• Bickel Elizabeth E., Lee Songhyun, Gounder Rajamani, Influence of Brønsted Acid-Site Density on Reaction-Diffusion Phenomena that Govern Propene Oligomerization Rate and Selectivity in MFI Zeolites, ACS Catalysis, 2, 1257-1269, (2023)
• Sawant Kaustubh J., Zeng Zhenhua, Greeley Jeffrey P., Universal properties of metal-supported oxide films from linear scaling relationships: elucidation of mechanistic origins of strong metal–support interactions, Chemical Science, 14(12), 3206–3214. (2023)
• Siddarth H. Krishna, Anshuman Goswami, Yujia Wang, Casey B. Jones, David P. Dean, Jeffrey T. Miller, William F. Schneider & Rajamani Gounder, Influence of framework Al density in chabazite zeolites on copper ion mobility and reactivity during NOx selective catalytic reduction with NH3, Nature Catalysis, 6(3), 276–285 (2023)
• Conrad Matthew A., DeLine Jaiden E., Miller Jeffrey T., High-Temperature Conversion of Olefins to Liquid Hydrocarbons on γ-Al2O3, Ind. Eng. Chem. Res., 2023
• Breckner Christian J., Zhu Kuixin, Wang Mingrui, Zhang Guanghui, Li Christina W., Miller Jeffrey T., Controlled site coverage of strong metal–support interaction (SMSI) on Pd NP catalysts, Catalysis Science & Technology, 1, 157-169, (2023)

2022(top)



• Yao Yonggang, Dong Qi, Brozena Alexandra, Luo Jian, Miao Jianwei, Chi Miaofang, Wang Chao, Kevrekidis Ioannis G., Ren Zhiyong Jason, Greeley Jeffrey, Wang Guofeng, Anapolsky Abraham, Hu Liangbing, High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery, Science, (2022)
• Chun Hee-Joon, Zeng Zhenhua, Greeley Jeffrey, DFT Insights into NO Electrochemical Reduction: A Case Study of Pt(211) and Cu(211) Surfaces, ACS Catalysis, 2, 1394-1402, 2022
• Ghanekar Pushkar G., Deshpande Siddharth, Greeley Jeffrey, Adsorbate chemical environment-based machine learning framework for heterogeneous catalysis, Nature Communications, 2022
• Kang Donghyeon, Warburton Robert E., Mane Anil U., Greeley Jeffrey, Elam Jeffrey W., Modification of LiMn2O4 surfaces by controlling the Acid–Base surface chemistry of atomic layer deposition, Applied Surface Science, (2022)
• Howard Jason D., Evmenenko Guennadi, Kim Jae Jin, Warburton Robert E., Patel Shane, Fister Timothy T., Buchholz D. Bruce, Greeley Jeffrey, Curtiss Larry A., Fenter Paul, Understanding the Solid-State Electrode–Electrolyte Interface of a Model System Using First-Principles Statistical Mechanics and Thin-Film X-ray Characterization, ACS Applied Materials & Interfaces, 5, 7428-7439, (2022)
• Zhao Qiyuan, Xu Yinan, Greeley Jeffrey, Savoie Brett M., Deep reaction network exploration at a heterogeneous catalytic interface, Nature Communications, 2022
• Xu Yinan, LiBretto Nicole J., Zhang Guanghui, Miller Jeffrey T., Greeley Jeffrey, First-Principles Analysis of Ethylene Oligomerization on Single-Site Ga³⁺ Catalysts Supported on Amorphous Silica, ACS Catalysis, 9, 5416-5424, 2022
• Milligan Cory A., Seemakurthi Ranga Rohit, Gao Junxian, Greeley Jeffrey P., Miller Jeffrey T., Ribeiro Fabio H., Zemlyanov Dmitry Y., Structure-Controlled Chemical Properties of PdZn Near-Surface Alloys, The Journal of Physical Chemistry C, 32, 13660-13674, (2022)
• Liu Guangdong, Deng Huiqiu, Greeley Jeffrey, Zeng Zhenhua, Density functional theory study of active sites and reaction mechanism of ORR on Pt surfaces under anhydrous conditions, Chinese Journal of Catalysis, 12, 3126-3133, 2022
• Conrad Matthew A., Shaw Alexander, Marsden Grant, Broadbelt Linda J., Miller Jeffrey T., Insights into the Chemistry of the Homogeneous Thermal Oligomerization of Ethylene to Liquid-Fuel-Range Hydrocarbons, Industrial & Engineering Chemistry Research, 5, 2202-2216, 2022
• Ma Rui, Gao Junxian, Kou Jiajing, Dean David P., Breckner Christian J., Liang Kaijun, Zhou Bo, Miller Jeffrey T., Zou Guojun, Insights into the Nature of Selective Nickel Sites on Ni/Al₂O₃ Catalysts for Propane Dehydrogenation, ACS Catalysis, 20, 12607-12616, (2022)
• Zhang Wenqing, Zhang Xiaoben, Wang Jianyang, Ghosh Arnab, Zhu Jie, LiBretto Nicole J., Zhang Guanghui, Datye Abhaya K., Liu Wei, Miller Jeffrey T., Bismuth-Modulated Surface Structural Evolution of Pd₃Bi Intermetallic Alloy Catalysts for Selective Propane Dehydrogenation and Acetylene Semihydrogenation, ACS Catalysis, 17, 10531-10545, 2022
• Lardinois Trevor M., Mandal Keka, Yadav Vamakshi, Wijerathne Asanka, Bolton Brandon K., Lippie Harrison, Li Christina W., Paolucci Christopher, Gounder Rajamani, Kinetic and Thermodynamic Factors Influencing Palladium Nanoparticle Redispersion into Mononuclear Pd(II) Cations in Zeolite Supports, The Journal of Physical Chemistry C, 19, 8337-8353, 2022
• Bickel Elizabeth E., Hoffman Alexander J., Lee Songhyun, Snider Hannah E., Nimlos Claire T., Zamiechowski Natalie K., Hibbitts David D., Gounder Rajamani, Altering the Arrangement of Framework Al Atoms in MEL Zeolites Using Mixtures of Tetrabutylammonium and Sodium Structure-Directing Agents, Chemistry of Materials, 15, 6835-6852, 2022
• Lee Songhyun, Nimlos Claire T., Kipp Elijah R., Wang Yujia, Gao Xuyao, Schneider William F., Lusardi Marcella, Vattipalli Vivek, Prasad Subramanian, Moini Ahmad, Gounder Rajamani, Evolution of Framework Al Arrangements in CHA Zeolites during Crystallization in the Presence of Organic and Inorganic Structure-Directing Agents, Crystal Growth & Design, 10, 6275-6295, 2022
• Bickel Elizabeth E., Gounder Rajamani, Hydrocarbon Products Occluded within Zeolite Micropores Impose Transport Barriers that Regulate Brønsted Acid-Catalyzed Propene Oligomerization, JACS Au, 11, 2585-2595, 2022
• Chang Che-Wei, Miller Jeffrey T., Catalytic process development strategies for conversion of propane to liquid hydrocarbons, Applied Catalysis A: General, 2022

2021(top)



• Richard Caulkins, Ravi Joshi, Gounder Rajamani, Fabio H. Ribeiro, (2021)Effects of Ethene Pressure on the Deactivation of Ni-Zeolites During Ethene Oligomerization at Sub-ambient Temperatures, ChemCatChem, 11, 2021
• Saxena Arunima, Joshi Ravi, Seemakurthi Ranga Rohit, Koninckx Elsa, Broadbelt Linda J., Greeley Jeffrey, Gounder Rajamani, (2021)Effect of Nickel Active Site Density on the Deactivation of Ni-Beta Zeolite Catalysts during Ethene Dimerization, ACS Engineering Au, 1, 2021
• Krishna, S. H., Jones, C. B., & Gounder, R. (2021). Temperature dependence of Cu(I) oxidation and Cu(II) reduction kinetics in the selective catalytic reduction of NOx with NH3 on Cu-chabazite zeolites. Journal of Catalysis, 404, 873–882. [Link]
• Chang, C.-W., Pham, H. N., Alcala, R., Datye, A. K., & Miller, J. T. (2021). Dehydroaromatization Pathway of Propane on PtZn/SiO2 + ZSM-5 Bifunctional Catalyst. ACS Sustainable Chemistry & Engineering, 10(1), 394–409. [Link]
• Warburton, R. E., Kim, J. J., Patel, S., Howard, J. D., Curtiss, L. A., Wolverton, C., … Greeley, J. (2021). Tailoring Interfaces in Solid-State Batteries Using Interfacial Thermochemistry and Band Alignment. Chemistry of Materials, 33(21), 8447–8459. [Link]
• Kou, J., Zhu Chen, J., Gao, J., Zhang, X., Zhu, J., Ghosh, A., … Miller, J. T. (2021). Structural and Catalytic Properties of Isolated Pt2+ Sites in Platinum Phosphide (PtP2). ACS Catalysis, 11(21), 13496–13509. [Link]
• Krishna, S. H., & Gounder, R. (2021). Molecular water provides a channel for communication between Brønsted acid sites in solid catalysts. Chem Catalysis, 1(5), 968–970. [Link]
• Pace, R. B., Lardinois, T. M., Ji, Y., Gounder, R., Heintz, O., & Crocker, M. (2021). Effects of Treatment Conditions on Pd Speciation in CHA and Beta Zeolites for Passive NOx Adsorption. ACS Omega, 6(44), 29471–29482. [Link]
• Wilcox, L. N., Krishna, S. H., Jones, C. B., & Gounder, R. (2021). Mechanistic studies of NH3-assisted reduction of mononuclear Cu(ii) cation sites in Cu-CHA zeolites. Catalysis Science & Technology, 11(24), 7932–7942. [Link]
• Li, Z., Xiao, Y., Chowdhury, P. R., Wu, Z., Ma, T., Chen, J. Z., … Varma, A. (2021). Direct methane activation by atomically thin platinum nanolayers on two-dimensional metal carbides. Nature Catalysis, 4(10), 882–891. [Link]
• Bregante, D. T., Wilcox, L. N., Liu, C., Paolucci, C., Gounder, R., & Flaherty, D. W. (2021). Dioxygen Activation Kinetics over Distinct Cu Site Types in Cu-Chabazite Zeolites. ACS Catalysis, 11(19), 11873–11884. [Link]
• Saxena, A., Joshi, R., Seemakurthi, R. R., Koninckx, E., Broadbelt, L. J., Greeley, J., & Gounder, R. (2021). Effect of Nickel Active Site Density on the Deactivation of Ni-Beta Zeolite Catalysts during Ethene Dimerization. ACS Engineering Au. [Link]
• Ju, L., Lin, Q., LiBretto, N. J., Wagner, C. L., Hu, C. T., Miller, J. T., & Diao, T. (2021). Reactivity of (bi-Oxazoline)organonickel Complexes and Revision of a Catalytic Mechanism. Journal of the American Chemical Society, 143(36), 14458–14463. [Link]
• Bickel, E. E., Nimlos, C. T., & Gounder, R. (2021). Developing quantitative synthesis-structure-function relations for framework aluminum arrangement effects in zeolite acid catalysis. Journal of Catalysis, 399, 75–85. [Link]
• Seemakurthi, R. R., Canning, G., Wu, Z., Miller, J. T., Datye, A. K., & Greeley, J. (2021). Identification of a Selectivity Descriptor for Propane Dehydrogenation through Density Functional and Microkinetic Analysis on Pure Pd and Pd Alloys. ACS Catalysis, 11(15), 9588–9604. [Link]
• Gao, J., Sawant, K. J., Miller, J. T., Zeng, Z., Zemlyanov, D., & Greeley, J. P. (2021). Structural and Chemical Transformations of Zinc Oxide Ultrathin Films on Pd(111) Surfaces. ACS Applied Materials & Interfaces, 13(29), 35113–35123. [Link]
• Zhu Chen, J., Talpade, A., Canning, G. A., Probus, P. R., Ribeiro, F. H., Datye, A. K., & Miller, J. T. (2021). Strong metal-support interaction (SMSI) of Pt/CeO2 and its effect on propane dehydrogenation. Catalysis Today, 371, 4–10. [Link]
• Krishna, S. H., Jones, C. B., & Gounder, R. (2021). Dynamic Interconversion of Metal Active Site Ensembles in Zeolite Catalysis. Annual Review of Chemical and Biomolecular Engineering, 12(1), 115–136. [Link]
• Dionigi, F., Zhu, J., Zeng, Z., Merzdorf, T., Sarodnik, H., Gliech, M., … Strasser, P. (2021). Intrinsic Electrocatalytic Activity for Oxygen Evolution of Crystalline 3d‐Transition Metal Layered Double Hydroxides. Angewandte Chemie International Edition, 60(26), 14446–14457. [Link]
• Cybulskis, V. J., Gawecki, P., Zvinevich, Y., Gounder, R., & Ribeiro, F. H. (2021). Demonstrating Concepts in Catalysis, Renewable Energy, and Chemical Safety with the Catalytic Oxidation of Hydrogen. Journal of Chemical Education, 98(6), 2036–2041. [Link]
• LiBretto, N. J., Xu, Y., Quigley, A., Edwards, E., Nargund, R., Vega-Vila, J. C., … Miller, J. T. (2021). Olefin oligomerization by main group Ga3+ and Zn2+ single site catalysts on SiO2. Nature Communications, 12(1). [Link]
• Cui, Y., Zhu Chen, J., Peng, B., Kovarik, L., Devaraj, A., Li, Z., … Gao, F. (2021). Onset of High Methane Combustion Rates over Supported Palladium Catalysts: From Isolated Pd Cations to PdO Nanoparticles. JACS Au, 1(4), 396–408. [Link]
• Kester, P. M., Crum, J. T., Li, S., Schneider, W. F., & Gounder, R. (2021). Effects of Brønsted acid site proximity in chabazite zeolites on OH infrared spectra and protolytic propane cracking kinetics. Journal of Catalysis, 395, 210–226. [Link]
• Talpade, A. D., Ghanekar, P., Ezenwa, S., Joshi, R., Kravitz, S., Tunga, A., … Mentzer, R. (2021). Promoting a Safe Laboratory Environment Using the Reactive Hazard Evaluation and Analysis Compilation Tool. ACS Chemical Health & Safety, 28(2), 134–143. [Link]
• Lardinois, T. M., Bates, J. S., Lippie, H. H., Russell, C. K., Miller, J. T., Meyer, H. M., … Gounder, R. (2021). Structural Interconversion between Agglomerated Palladium Domains and Mononuclear Pd(II) Cations in Chabazite Zeolites. Chemistry of Materials, 33(5), 1698–1713. [Link]
• Bates, J. S., & Gounder, R. (2021). Kinetic effects of molecular clustering and solvation by extended networks in zeolite acid catalysis. Chemical Science, 12(13), 4699–4708. [Link]
• Bukowski, B. C., Delgass, W. N., & Greeley, J. (2021). Gold Stability and Diffusion in the Au/TS-1 Catalyst. The Journal of Physical Chemistry C, 125(8), 4519–4531. [Link]
• Samira, S., Deshpande, S., Greeley, J., & Nikolla, E. (2021). Aprotic Alkali Metal–O2 Batteries: Role of Cathode Surface-Mediated Processes and Heterogeneous Electrocatalysis. ACS Energy Letters, 6(2), 665–674. [Link]
• Vernuccio, S., Bickel, E. E., Gounder, R., & Broadbelt, L. J. (2021). Propene oligomerization on Beta zeolites: Development of a microkinetic model and experimental validation. Journal of Catalysis, 395, 302–314. [Link]

2020(top)



• Chun, H.-J., Zeng, Z., & Greeley, J. (2020). Direct Demonstration of Unified Brønsted−Evans−Polanyi Relationships for Proton-Coupled Electron Transfer Reactions on Transition Metal Surfaces. Journal of The Electrochemical Society, 167(16), 166516. [Link]
• Mitchell, G. M., Sabnis, K. D., Sollberger, F. G., Cui, Y., Han, C. W., Majumdar, P., … Ribeiro, F. H. (2020). Effect of cobalt addition on platinum supported on multi-walled carbon nanotubes for water-gas shift. Journal of Catalysis, 391, 25–34. [Link]
• Yadav, V., Lowe, J. S., Shumski, A. J., Liu, E. Z., Greeley, J., & Li, C. W. (2020). Modulating the Structure and Hydrogen Evolution Reactivity of Metal Chalcogenide Complexes through Ligand Exchange onto Colloidal Au Nanoparticles. ACS Catalysis, 10(22), 13305–13313. [Link]
• Bates, J. S., & Gounder, R. (2020). Clustering of alkanols confined in chabazite zeolites: Kinetic implications for dehydration of methanol-ethanol mixtures. Journal of Catalysis, 390, 178–183. [Link]
• Zhu Chen, J., Talpade, A., Canning, G. A., Probus, P. R., Ribeiro, F. H., Datye, A. K., Miller, J. T. (2020) Strong Metal-Support Interaction (SMSI) of Pt/CeO2 and Its Effect on Propane Dehydrogenation. Catalysis Today [Link]
• Nimlos, C. T., Hoffman, A. J., Hur, Y. G., Lee, B. J., Di Iorio, J. R., Hibbitts, D. D., & Gounder, R. (2020). Experimental and Theoretical Assessments of Aluminum Proximity in MFI Zeolites and Its Alteration by Organic and Inorganic Structure-Directing Agents. Chemistry of Materials, 32(21), 9277–9298. [Link]
• Warburton, R. E., Castro, F. C., Deshpande, S., Madsen, K. E., Bassett, K. L., dos Reis, R., … Greeley, J. (2020). Oriented LiMn2O4 Particle Fracture from Delithiation-Driven Surface Stress. ACS Applied Materials & Interfaces, 12(43), 49182–49191. [Link]
• Vega-Vila, J. C., & Gounder, R. (2020). Quantification of Intraporous Hydrophilic Binding Sites in Lewis Acid Zeolites and Consequences for Sugar Isomerization Catalysis. ACS Catalysis, 10(20), 12197–12211. [Link]
• Paolucci, C., Di Iorio, J. R., Schneider, W. F., & Gounder, R. (2020). Solvation and Mobilization of Copper Active Sites in Zeolites by Ammonia: Consequences for the Catalytic Reduction of Nitrogen Oxides. Accounts of Chemical Research, 53(9), 1881–1892. [Link]
• Joshi, R., Saxena, A., & Gounder, R. (2020). Mechanistic insights into alkene chain growth reactions catalyzed by nickel active sites on ordered microporous and mesoporous supports. Catalysis Science & Technology, 10(21), 7101–7123. [Link]
• Harris, J. W., Bates, J. S., Bukowski, B. C., Greeley, J., & Gounder, R. (2020). Opportunities in Catalysis over Metal-Zeotypes Enabled by Descriptions of Active Centers Beyond Their Binding Site. ACS Catalysis, 10(16), 9476–9495. [Link]
• Deshpande, S., & Greeley, J. (2020). First-Principles Analysis of Coverage, Ensemble, and Solvation Effects on Selectivity Trends in NO Electroreduction on Pt3Sn Alloys. ACS Catalysis, 10(16), 9320–9327. [Link]
• Bates, J. S., Bukowski, B. C., Greeley, J., & Gounder, R. (2020). Correction: Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis. Chemical Science, 11(31), 8323–8324. [Link]
• Hoffman, A. J., Bates, J. S., Di Iorio, J. R., Nystrom, S. V., Nimlos, C. T., Gounder, R., & Hibbitts, D. (2020). Rigid Arrangements of Ionic Charge in Zeolite Frameworks Conferred by Specific Aluminum Distributions Preferentially Stabilize Alkanol Dehydration Transition States. Angewandte Chemie International Edition, 59(42), 18686–18694. [Link]
• Harris, J. W., Bates, J. S., Bukowski, B. C., Greeley, J., & Gounder, R. (2020). Opportunities in Catalysis over Metal-Zeotypes Enabled by Descriptions of Active Centers Beyond Their Binding Site. ACS Catalysis, 10(16), 9476–9495. [Link]
• Bates, J. S., Bukowski, B. C., Greeley, J., & Gounder, R. (2020). Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis. Chemical Science, 11(27), 7102–7122. [Link]
• Krishna, S. H., Jones, C. B., Miller, J. T., Ribeiro, F. H., & Gounder, R. (2020). Combining Kinetics and Operando Spectroscopy to Interrogate the Mechanism and Active Site Requirements of NOx Selective Catalytic Reduction with NH3 on Cu-Zeolites. The Journal of Physical Chemistry Letters, 11(13), 5029–5036. [Link]
• Kester, P. M., Iglesia, E., & Gounder, R. (2020). Parallel Alkane Dehydrogenation Routes on Brønsted Acid and Reaction-Derived Carbonaceous Active Sites in Zeolites. The Journal of Physical Chemistry C, 124(29), 15839–15855. [Link]
• Bates, J. S., Bukowski, B. C., Greeley, J., & Gounder, R. (2020). Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis. Chemical Science, 11(27), 7102–7122. [Link]
• Cordon, M. J., Vega‐Vila, J. C., Casper, A., Huang, Z., & Gounder, R. (2020). Tighter Confinement Increases Selectivity of d‐Glucose Isomerization Toward l‐Sorbose in Titanium Zeolites. Angewandte Chemie International Edition, 59(43), 19102–19107. [Link]
• Deshpande, S., Maxson, T., & Greeley, J. (2020). Graph theory approach to determine configurations of multidentate and high coverage adsorbates for heterogeneous catalysis. Npj Computational Materials, 6(1). [Link]
• Jones, C. B., Khurana, I., Krishna, S. H., Shih, A. J., Delgass, W. N., Miller, J. T., … Gounder, R. (2020). Effects of dioxygen pressure on rates of NOx selective catalytic reduction with NH3 on Cu-CHA zeolites. Journal of Catalysis, 389, 140–149. [Link]
• Dionigi, F., Zeng, Z., Sinev, I., Merzdorf, T., Deshpande, S., Lopez, M. B., … Strasser, P. (2020). In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution. Nature Communications, 11(1). [Link]
• Purdy, S. C., Seemakurthi, R. R., Mitchell, G. M., Davidson, M., Lauderback, B. A., Deshpande, S., … Miller, J. T. (2020). Structural trends in the dehydrogenation selectivity of palladium alloys. Chemical Science, 11(19), 5066–5081. [Link]
• Ghanekar, P., Kubal, J., Cui, Y., Mitchell, G., Delgass, W. N., Ribeiro, F., & Greeley, J. (2020). Catalysis at Metal/Oxide Interfaces: Density Functional Theory and Microkinetic Modeling of Water Gas Shift at Pt/MgO Boundaries. Topics in Catalysis, 63(7-8), 673–687. [Link]
• Majidi, L., Hemmat, Z., Warburton, R. E., Kumar, K., Ahmadiparidari, A., Hong, L., … Salehi-Khojin, A. (2020). Highly Active Rhenium-, Ruthenium-, and Iridium-Based Dichalcogenide Electrocatalysts for Oxygen Reduction and Oxygen Evolution Reactions in Aprotic Media. Chemistry of Materials, 32(7), 2764–2773. [Link]
• Wegener, E. C., Bukowski, B. C., Yang, D., Wu, Z., Kropf, A. J., Delgass, W. N., … Miller, J. T. (2020). Intermetallic Compounds as an Alternative to Single‐atom Alloy Catalysts: Geometric and Electronic Structures from Advanced X‐ray Spectroscopies and Computational Studies. ChemCatChem, 12(5), 1325–1333. [Link]
• Warburton, R. E., Young, M. J., Letourneau, S., Elam, J. W., & Greeley, J. (2020). Descriptor-Based Analysis of Atomic Layer Deposition Mechanisms on Spinel LiMn2O4 Lithium-Ion Battery Cathodes. Chemistry of Materials, 32(5), 1794–1806. [Link]
• Di Iorio, J. R., Li, S., Jones, C. B., Nimlos, C. T., Wang, Y., Kunkes, E., … Gounder, R. (2020). Cooperative and Competitive Occlusion of Organic and Inorganic Structure-Directing Agents within Chabazite Zeolites Influences Their Aluminum Arrangement. Journal of the American Chemical Society, 142(10), 4807–4819. [Link]
• Purdy, S. C., Ghanekar, P., Mitchell, G., Kropf, A. J., Zemlyanov, D. Y., Ren, Y., … Miller, J. T. (2020). Origin of Electronic Modification of Platinum in a Pt3V Alloy and Its Consequences for Propane Dehydrogenation Catalysis. ACS Applied Energy Materials, 3(2), 1410–1422. [Link]
• Cybulskis, V. J., Gounder, R., Mojarad, S., & Davis, M. E. (2020). Initiating a research‐focused academic career in chemical engineering: Perspectives from faculty at different career stages. AIChE Journal, 66(4). [Link]
• Ganesh, H. S., Dean, D. P., Vernuccio, S., Edgar, T. F., Baldea, M., Broadbelt, L. J., … Allen, D. T. (2020). Product Value Modeling for a Natural Gas Liquid to Liquid Transportation Fuel Process. Industrial & Engineering Chemistry Research, 59(7), 3109–3119. [Link]



2019(top)



• A. Cross, A. Yeghishyan, K. Manukyan, J.T. Miller, D. Rensel, V. Danghyan, A.S. Mukasyan, E.E. Wolf, “Active and Stable Ni and Ni-Cu Supported Catalysts for Hydrogen Production from Ethanol prepared by Combustion Synthesis,” Appl. Catal. A, Gen., 572, 124-133 (2019).[Link]
• A. J. Shih, I. Khurana, H. Li, J. González, A. Kumar, C. Paolucci, T. M. Lardinois, C. B. Jones, J. D. Albarracin-Caballero, K. Kamasamudram, A. Yezerets, W. N. Delgass, J. T. Miller, A. L. Villa, W. F. Schneider*, R. Gounder*, F. H. Ribeiro*, "Spectroscopic and Kinetic Responses of Cu-SSZ-13 to SO2 Exposure and Implications for NOx Selective Catalytic Reduction", Applied Catalysis A, 574 (2019) 122-131[Link]
• C. Yang, Z. Wu, G. Zhang, H. Sheng, J. Tian, Z. Duan, H. Sohn, A.J.Kropf, T. Wu, T.R. Krause, J.T. Miller, “Promotion of Pd Nanoparticles by Fe and Formation of a Pd3Fe Intermetallic Alloy for Propane Dehydrogenation,” Catal. Today, 323, 123-128 (2019).[Link]
• D. Kunwar, S. Zhou, A. De La Riva, E. Peterson, H. Xiong, Pereira Hernandez, X.I.P. Hernandez, S.C, Purdy, R. ter Veen, H. Brongersma, J.T. Miller, H. Hashiguchi L. Kovarik, S. Lin, H. Guo, Y. Wang, A. Datye, “Stabilizing High Metal Loadings of Thermally Stable Platinum Single Atoms on an Industrial Catalyst Support,” ACS Catal. 2019[Link]
• D. T. Bregante, A. M. Johnson, A, Y. Patel, E. Z. Ayla, M. J. Cordon, B. C. Bukowski, J. Greeley, R. Gounder, D. W. Flaherty*, "Cooperative Effects Between Hydrophilic Pores and Solvents: Catalytic Consequences of Hydrogen-Bonding on Alkene Epoxidation in Zeolites", Journal of the American Chemical Society, 141 (2019) 7302-7319 [Link]
• D.J. Deka, S. Gunduz, T. Fitzgerald, J.T. Miller, A.C. Co, U.S. Ozkan, “Production of Syngas with Controllable H2/CO ratio by High Temperature Co-Electrolysis of CO2 and H2O over Ni and Co Doped Lanthanum Strontium Ferrite Perovskite Cathodes,” Appl. Catal. B: Env., 248, 487-503 (2019).[Link]
• G. Celik, S.A. Ailawar, S. Gunduz, J.T. Miller, P.L. Edmiston, U.S. Ozkan, “Aqueous-Phase Hydrodechlorination of Trichloroethylene over Pd-based Swellable Organically-Modified Silica (SOMS): Catalyst Deactivation Due to Sulfur Species,” Industrial & Engineering Chemistry Research, 58 (10), 4054–4064 (2019).[Link]
• G. Evmenenko, R.E. Warburton, H. Yildirim, J. Greeley, M.K.Y. Chan, D.B. Buchholz, P. Fenter, M.J. Bedzyk, T.T. Fister, Understanding the Role of Overpotentials in Lithium Ion Conversion Reactions: Visualizing the Interface, ACS Nano (2019)[Link]
• G. Zhang, C. Ye, W. Liu, X. Zhang, D. Su, X. Yang, J. Zhu Chen, Z. Wu, J. T. Miller, "Diffusion-Limited Formation of Nonequilibrium Intermetallic Nanophase for Selective Dehydrogenation," Nano Lett. 2019[Link]
• H. Li, C. Paolucci, I. Khurana, L. N. Wilcox, F. Göltl, J. D. Albarracin-Caballero, A. J. Shih, F. H. Ribeiro, R. Gounder and W. F. Schneider, Consequences of exchange-site heterogeneity and dynamics on the UV-visible spectrum of Cu-exchanged SSZ-13, Chemical Science, 10 (2019) 2373-2384[Link]
• H. Li^, C. Paolucci^, I. Khurana, L. N. Wilcox, F. Göltl, J. D. Albarracin-Caballero, A. J. Shih, F. H. Ribeiro, R. Gounder*, W. F. Schneider*, "Consequences of Exchange-Site Heterogeneity and Dynamics on the UV-Visible Spectrum of Cu-Exchanged SSZ-13", Chemical Science, 10 (2019) 2373-2384 [Link]
• J. S. Bates, B. C. Bukowski, J. W. Harris, J. Greeley, R. Gounder*, "Distinct Catalytic Reactivity of Sn Substituted in Framework Locations and at Defect Grain Boundaries in Sn-Zeolites", ACS Catalysis (2019) DOI:10.1021/acscatal.9b01123 [Link]
• J. Zhuchen, Z. Wu, X. Zhang, S. Choi, Y. Xiao, A. Varma, W. Liu, G. Zhang, J.T. Miller, “Identification of the Structure of the Bi Promoted Pt Non-oxidative Coupling of Methane Catalyst: A Nanoscale Pt3Bi Intermetallic Alloy,” Catal. Sci & Tech, 9, 1349-1356 (2019).[Link]
• K. Roy, L. Artiglia, Y. Xiao, A. Varma, and J. van Bokhoven, Role of Bismuth in the Stability of Pt–Bi Bimetallic Catalyst for Methane Mediated Deoxygenation of Guaiacol, an APXPS Study, ACS Catalysis, 9 (2019) 3694-3699,[Link]
• K.L. Bassett, R.E. Warburton, S. Deshpande, T.T. Fister, K. Ta, J.L. Esbenshade, A. Kinaci, M.K.Y. Chan, K.M. Wiaderek, K.W. Chapman, J.P. Greeley, A.A. Gewirth, Operando Observations and First-Principles Calculations of Reduced Bulk Lithium Insertion in Au-Coated LiMn2O4, Advanced Materials Interfaces 6(4) (2019) 1801923[Link]
• L. Majidi, P. Yasaei, R.E. Warburton, S. Fuladi, J. Cavin, X. Hu, Z. Hemmat, S.B. Cho, P. Abbasi, M. Vörös, L. Cheng, B. Sayahpour, I.L. Bolotin, P. Zapol, J. Greeley, R.F. Klie, R. Mishra, F. Khalili-Araghi, L.A. Curtiss, A. Salehi-Khojin, New Class of Electrocatalysts based on 2-D Transition Metal Dichalcogenides in Ionic Liquid, Advanced Materials 31(4) (2019) 1804453 [Link]
• M. J. Cordon, J. N. Hall, J. W. Harris, J. S. Bates, S.-J. Hwang, R. Gounder*, "Deactivation of Sn-Beta Zeolites Caused by Structural Transformation of Hydrophobic to Hydrophilic Micropores During Aqueous-Phase Glucose Isomerization", Catalysis Science & Technology, 9 (2019) 1654-1668[Link]
• N.J. LiBretto, C. Yang, Y. Ren, G. Zhang, J.T. Miller, “Identification of Surface Structures in Pt3Cr Intermetallic Nano-catalysts,” Chem. Mat., 31 (5), pp 1597–1609 (2019).[Link]
• R. Gounder*, A. Moini*, "Automotive NOx Abatement Using Zeolite-Based Technologies", Reaction Chemistry & Engineering, 4 (2019) 966-968[Link]
• Z. Zhao, K.N. Heck, P. Limpornpipat, H. Qian, J.T. Miller, M.S. Wong, “Hydrogen-generating behavior of Pd-decorated gold nanoparticles via formic acid decomposition,” Catal. Today, 330, 24-31 (2019).[Link]



2018(top)



• A.M. Wright, Z. Wu, G. Zhang, J.L. Mancuso, R.J. Comito, C.H. Hendon, J.T. Miller, M. Dincă, “A structural mimic of carbonic anhydrase in a metal-organic framework,” Chem. Chem., 4(12), 2894-2901 (2018).[Link]
• B. C. Bukowski, J. S. Bates, R. Gounder, J. Greeley*, "First Principles, Microkinetic, and Experimental Analysis of Lewis Acid Site Speciation During Ethanol Dehydration on Sn-Beta Zeolites", Journal of Catalysis, 365 (2018) 261-276[Link]
• B. C. Knott^, C. T. Nimlos^, D. J. Robichaud, M. R. Nimlos, S. Kim*, R. Gounder*, "Consideration of the Aluminum Distribution in Zeolites in Theoretical and Experimental Catalysis Research", ACS Catalysis, 8 (2018) 770-784[Link]
• C. Ye, Z. Wu, W. Liu, Y. Ren, G. Zhang, J.T. Miller, “Structure Determination of a Novel Surface Tetragonal Pt1Sb1 Phase on Pt Nanoparticles,” Chem. Mat., 30 (14), 4503-4507 (2018).[Link]
• D. Jung, L.M.A. Saleh, Z. Berkson, J.Y. Hwang, M.F. El-Kady, E. Titarenko, Y. Shao, K. McCarthy, A.I. Wixtrom, J. Guo, I.B. Martini, S. Kraemer, E.C. Wegener, P. Saint-Cricq, R.R. Langeslay, M. Delferro, J.L. Brosmer, K.W. Chapman, J.T. Miller, X. Duan, R.B. Kaner, J.I. Zink, B.F. Chmelka, A.M. Spokoyny, “Molecular Doping Approach for Hybrid Metal Oxide Materials,” Nature Materials., 17, 341–348 (2018).[Link]
• E.C. Wegener, Z. Wu, H.-T. Tseng, J.R. Gallagher, Y. Ren, R.E. Diaz, F.H. Ribeiro, J.T. Miller, “Structure and reactivity of Pt-In intermetallic alloy nanoparticles: highly selective catalysts for ethane dehydrogenation,” Catal. Today, 299 146-153 (2018).[Link]
• G. Celik, S. Gunduz, S.A. Ailawar, J.T. Miller, P.L. Edmiston, U.S. Ozkan, “Aqueous-Phase Hydrodechlorination of Trichloroethylene over Pd-based Swellable Organically-Modified Silica (SOMS): Catalyst Deactivation Due to Chloride Anions,” Appl. Catal. B: Env., 239, 654-664 (2018).[Link]
• G. Celik, S.A. Ailawar, H. Sohn, Y. Tang, F. Tao, J.T. Miller, P.L. Edmiston, U.S. Ozkan, “Swellable Organically-modified Silica (SOMS) as a Novel Catalyst Scaffold for Catalytic Treatment of Water Contaminated with Trichloroethylene,” ACS Catal. 8 (8), 6796–6809 (2018).[Link]
• G. Spezzati, A. Benavidez, A.T. DeLaRiva, Y. Su, J.P. Hofmann, S. Asahina, E.J. Olivier, J.H. Neethling, J.T. Miller, A.K. Datye, E.J.M. Hensen, “ On the Difference Between Pd Supported on CeO2(100) and CeO2(111) Facets for CO Oxidation Catalysis,” Appl. Catal. B: Env., 243, 36-46 (2018).[Link]
• G. Sun, Z.-J. Zhao, R. Mu, S. Zha, L. Li, S. Chen, K. Zang, J. Luo, Z. Li, S. Purdy, A.J. Kropf, J.T. Miller, L. Zeng, J. Gong, “Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for propane dehydrogenation,” Nature Communications 9(1): 4454 (2018):[Link]
• G. Zhang, C. Yang, J.T. Miller, “Tetrahedral Nickel(II) Phosphosilicate Single Site Selective Propane Dehydrogenation Catalyst,” ChemCatChem, 10(5), 961-964 (2018).[Link]
• J. S. Bates, R. Gounder*, "Influence of Confining Environment Polarity on Ethanol Dehydration Catalysis by Lewis Acid Zeolites", Journal of Catalysis, 365 (2018) 213-226[Link]
• K. Liu, C. Zhang, Y. Sun, G. Zhang, X. Shen, F. Zou, H. Zhang, Z. Wu, E.C. Wegener, C. Taubert, J.T. Miller, Z. Peng, Yu Zhu, “Self-assembled Hollow Transition Metal Phosphide Alloy for Enhanced Oxygen Evolution Reaction,” ACS Nano, 12 (1), 158–167 (2018).[Link]
• L. Chen, R.E. Warburton, K.-S. Chen, J.A. Liberia, C. Johnson, Z. Yang, M.C. Hersam, J.P. Greeley, J.W. Elam, Mechanism for Al2O3 Atomic Layer Deposition on LiMn2O4 from In Situ Measurement and Ab Initio Calculations, Chem 4(10) (2018) 2418-2435[Link]
• M. J. Cordon, J. W. Harris, J. C. Vega-Vila, J. S. Bates, S. Kaur, M. Gupta, M. E. Witzke, E. C. Wegener, J. T. Miller, D. W. Flaherty, D. D. Hibbitts, R. Gounder*, "Dominant Role of Entropy in Stabilizing Sugar Isomerization Transition States within Hydrophobic Zeolite Pores", Journal of the American Chemical Society, 140 (2018), 14244-14266[Link]
• M.J. Cordon, J.W. Harris, J.C. Vega-Vila, J.S. Bates, S. Kaur, M. Gupta, M.E. Witzke, E.C. Wegener, J.T. Miller, D.W. Flaherty, D.D. Hibbitts, R. Gounder, “The Dominant Role of Entropy in Stabilizing Sugar Isomerization Transition States within Hydrophobic Zeolite Pores,” JACS, 140 (43), 14244–14266, (2018).[Link]
• M.N. Jackson, S. Oh, C.J. Kaminsky, S.B. Chu, G. Zhang, J.T. Miller, Y. Surendranath, “Strong electronic coupling of molecular sites to graphitic electrodes via pyrazine conjugation,” JACS, 140 (3), 1004–1010 (2018).[Link]
• N.M. Briggs, L. Barrett, E.C. Wegener, L.V. Herrera, L.A. Gomez, J.T. Miller, S.P. Crossley, “Identification of Active Sites on Supported Metal Catalysts with Carbon Nanotube Hydrogen Highways,” Nature Communications, 9(1), 3827 (2018).[Link]
• P. M. Kester, J. T. Miller, R. Gounder*, "Ammonia Titration Methods to Quantify Brønsted Acid Sites in Zeolites Substituted with Aluminum and Boron Heteroatoms", Industrial & Engineering Chemistry Research, 57 (2018) 6673-6683[Link]
• P. Xie, T. Pu, A. Nie, S. Hwang, S.C. Purdy, W. Yu, D. Su, J.T. Miller, C. Wang, “Nanoceria Supported Atomic Platinum Catalysts for Direct Methane Conversion,” ACS Catal., 8, 4044-4048 (2018).[Link]
• P.M. Kester, J.T. Miller, R. Gounder, “Ammonia Titration Methods to Quantify Brønsted Acid Sites in Zeolites Substituted with Aluminum and Boron Heteroatoms,” submitted Ind. Eng. & Chem. Res., 57 (19), 6673–6683 (2018).[Link]
• R. Joshi, G. Zhang, J. T. Miller, R. Gounder*, "Evidence for the Coordination-Insertion Mechanism of Ethene Dimerization at Nickel Cations Exchanged onto Beta Molecular Sieves", ACS Catalysis, 8 (2018) 11407-11422[Link]
• R.J. Comito, Z. Wu, G, Zhang, J.A. Lawrence, M. Korzyński, J.A. Kehl, J.T. Miller, M. Dincă, “Stabilized Vanadium Catalyst for Olefin Polymerization by Site Isolation in a Metal-Organic Framework,” Angew. Chem. Int. Ed., 57, 8135 –8139 (2018).[Link]
• S. Ana, G. Zhang, T. Wanga, W. Zhang, K. Lia, C. Song, J.T. Miller, S. Miao, J. Wang, X. Guo, “High‐density Ultrasmall Cluster and Single‐atom Fe Sites Embedded in g‐C3N4 for Highly Efficient Catalytic Advanced Oxidation Processes,” ACS Nano, 12, 9441−9450 (2018).[Link]
• S. Chattopadhyay, S.G. Kwon, E.V. Shevchenko, J.T. Miller, S.M. Heald, “In situ X-ray Absorption Spectroscopy Studies of Functional Nanomaterials,” in Chapter 5 in In-situ Characterization Techniques for Nanomaterials, Kumar, C.S.S.R. (Ed.), Springer, Berlin, Heidelberg, 159-188 (2018).[Link]
• S. Guo, K. Heck, S. Kasiraju, H. Qian, Z. Zhao, L.C. Grabow, J.T. Miller, M.S. Wong, “Insights into Nitrate Degradation over Indium-decorated Palladium Nanoparticle Catalysts,” ACS Catal, 8 (1), 503–515 (2018).[Link]
• S. Li, H. Li, R. Gounder, A. Debellis, I. B. Müller, S. Prasad, A. Moini, W. F. Schneider*, "First-Principles Comparison of Proton and Divalent Copper Cation Exchange Energy Landscapes in SSZ-13 Zeolite", Journal of Physical Chemistry C, 122 (2018) 23564-23573[Link]
• T. Ridha, Y. Li, E. Gençer , J.J. Siirola, J.T. Miller , F.H. Ribeiro, Rakesh Agrawal, “Valorization of Shale Gas Condensate to Liquid Hydrocarbons through Catalytic Dehydrogenation and Oligomerization,” Processes, 6, 139 (2018).[Link]
• X. Shen, C. Zhang, S. Zhang, S. Dai, G. Zhang, M. Ge, Y. Pan, S.M. Sharkey, G.W. Graham, A. Hunt, I. Waluyo, J.T. Miller, X. Pan, Z. Peng, “Deconvolution of octahedral Pt3Ni nanoparticle growth pathway from in situ characterizations,” Nature Communications, 9, 4485 (2018)[Link]
• Y. Xiao and A. Varma, Bio-Oil Upgrading Using Methane: A Mechanistic Study of Reactions of Model Compound Guaiacol over Pt–Bi Bimetallic Catalysts, ACS Sustainable Chemistry & Engineering, 6 (2018) 17368-17375[Link]
• Y. Xiao and A. Varma, Highly Selective Nonoxidative Coupling of Methane over Pt-Bi Bimetallic Catalysts, ACS Catalysis, 8 (2018) 2735-2740[Link]
• Y. Xiao, Y. Wang and A. Varma, Low-temperature selective oxidation of methanol over Pt-Bi bimetallic catalysts, Journal of Catalysis, 363 (2018) 144-153[Link]
• Z. Li, L. Yu, C. Milligan, T. Ma, L.Zhou, Y. Cui, Z. Qi, B. Xu, J. Luo, E. Shi, Z. Wu, H. Xin, W.N. Delgass, J.T. Miller, Y. Wu, “Two-dimensional Transition Metal Carbides as Supports for Tuning the Chemistry of Catalytic Nano-particles,” Nature Communications, 9, 5258 (2018)[Link]
• Z. Li, Y. Cui, Z. Wu, C. Milligan, L. Zhou, G. Michell, B. Xu, E. Shi, J.T. Miller, F.H. Ribeiro, Y. Wu, “Reactive metal–support interactions at moderate temperature in two-dimensional niobium-carbide supported platinum catalysts,” Nature Catalysis, 1, 349–355 (2018).[Link]
• Z. Wu, B.C. Bukowski, Z. Li, C. Milligan, L. Zhou, T. Ma, Y. Wu, Y. Ren, F.H. Ribeiro, W.N. Delgass, J. Greeley, G. Zhang, J.T. Miller, “Changes in Catalytic and Adsorptive Properties of 2 nm Pt3Mn Nanoparticles by Subsurface Atoms,” JACS, 140(44), 14870-14877 (2018).[Link]



2017(top)



• A.J. Getsoian, B. Hu, J.T. Miller, A.S. Hock, “Silica-Supported, Single Site Sc and Y Alkyls for Catalytic Hydrogenation of Propylene,” Organometallics, 36 (19), 3677–3685 (2017).[Link]
• C. Paolucci, I. Khurana, A. A. Parekh, S. Li, A. J. Shih, H. Li, J. R. Di Iorio, J. D. Albarracin-Caballero, A. Yezerets, J. T. Miller, W. N. Delgass, F. H. Ribeiro, W. F. Schneider*, R. Gounder*, "Dynamic Multinuclear Sites Formed by Mobilized Copper Ions in NOx Selective Catalytic Reduction", Science, 357 (2017) 898-903 [Link]
• C. Paolucci, I. Khurana, A.A. Parekh, S. Li, A.J. Shih, H. Li, J.R. Di Iorio, J. Albarracin, A. Yezerets, J.T. Miller, W.N. Delgass, F.H. Ribeiro, W.F. Schneider, R. Gounder, “Dynamic Multi-nuclear Sites Formed by Mobilized Copper Ions in NOx Selective Catalytic Reduction,” Science, 357, 6354 898-903 (2017).[Link]
• C.A. Farberow, S. Cheah, S. Kim, J.T. Miller, J.R. Gallagher, J.E. Hensley, J.A. Schaidle, D.A. Ruddy, “Exploring low-temperature dehydrogenation at ionic Cu sites to enable alkane recycle in DME homologation,” ACS Catal., 7, 3662–3667 (2017).[Link]
• J. Camacho-Bunquin, M. Ferrandon, U. Das, F. Dogan, C. Liu, C. Larsen, L.A. Curtiss, J.T. Miller, A.S. Hock, S. Nguyen, C.L. Marshall, P.C. Stair, “Supported Aluminum Catalysts for Olefin Hydrogenation,” ACS Catal., 7, 689–694 (2017).[Link]
• J. Camacho-Bunquin, P. Aich, M. Ferrandon, A.G. Getsoian, U. Das, F. Dogan, L.A. Curtiss, J.T. Miller, C.L. Marshall, A.S. Hock, P.C. Stair, “Single-Site Zinc on Silica Catalysts for Propylene Hydrogenation and Propane Dehydrogenation. Synthesis and Reactivity Evaluation Using an Integrated Atomic Layer Deposition-Catalysis Instrument,” J. Catal., 345, 170-182 (2017).[Link]
• J. D. Albarracin-Caballero, I. Khurana, J. R. Di Iorio, A. J. Shih, J. E. Schmidt, M. Dusselier, M. E. Davis, A. Yezerets, J. T. Miller, F. H. Ribeiro*, R. Gounder*, "Structural and Kinetic Changes to Small-Pore Cu-Zeolites After Hydrothermal Aging Treatments and Selective Catalytic Reduction of NOx with Ammonia", Reaction Chemistry & Engineering, 2 (2017) 168-179[Link]
• J. R. Di Iorio, C. T. Nimlos, R. Gounder*, "Introducing Catalytic Diversity into Single-Site Chabazite Zeolites of Fixed Composition via Synthetic Control of Active Site Proximity", ACS Catalysis, 7 (2017) 6663-6674[Link]
• J. W. Harris^, W.-C. Liao^, J. R. Di Iorio, A. M. Henry, T.-C. Ong, A. Comas-Vives, C. Copèret*, R. Gounder*, "Molecular Structure and Confining Environment of Sn Sites in Single-Site Chabazite Zeolites", Chemistry of Materials, 29 (2017) 8824-8837[Link]
• J.D. Albarracin-Caballero, I. Khurana, J.R. Di Iorio, A.J. Shih, J.E. Schmidt, M. Dusselier, M.E. Davis, A. Yezerets, J.T. Miller, F.H. Ribeiro, R. Gounder, “Structural and Kinetic Changes to Small-Pore Cu-Zeolites after Hydrothermal Aging Treatments and Selective Catalytic Reduction of NOx with Ammonia,” React. Eng. Chem., 2, 168-179 (2017).[Link]
• K.R. Pichaandi, L. Kabalan, H. Amini, G. Zhang, H. Zhi, H.I. Kentamma, P. Fanwick, J.T. Miller, S. Kais, M. Rashdi, S.M. Nabavizadeh, M. M. Abu-Omar, “Mechanism of Me-Re Bond Addition to Platinum(II) and Dioxygen Activation by the Resulting Pt-Re Bimetallic Center,” Inorg. Chem., 56, 2145-2152 (2017).[Link]
• O.O. Adigun, E.L. Retzlaff-Roberts, G. Novikova, L. Wang, B.S. Kim, J. Ilavsky, J.T. Miller, L.S. Loesch-Fries, M.T. Harris, “BSMV as a Novel Biotemplate for Palladium Nanomaterial Synthesis,” Langmuir, 33, 1716-1724 (2017).[Link]
• P. Murria, C. Miskin, R. Boyne, L. Cain, R. Yerabolu, R. Zhang, E.C. Wegener, J.T. Miller, H. Kenttamaa, R. Agrawal, “Speciation of CuCl and CuCl2 Thiol-Amine Solutions and Characterization of Resulting Films: Implications for Semiconductor Device Fabrication,” Inorg. Chem., 56(23), 14396-14407 (2017).[Link]
• R. Dubey, R. Comito, Robert, Z. Wu, G. Zhang, A. Rieth, C. Hendon, J.T. Miller, M. Dinca, “Highly Stereoselective Heterogeneous Diene Polymerization by Co-MFU-4l: A Single-Site Catalyst Prepared by Cation Exchange,” JACS, 139(36), 12664-12669 (2017).[Link]
• R.J. Comito, E.D. Metzger, Z. Wu, G. Zhang, C.H. Hendon, J.T. Miller, M. Dincă, “Selective Dimerization of Propylene with Ni-MFU-4l,” Organometallics, 36 (9), 1681–1683 (2017).[Link]
• V.J. Cybulskis, B.C. Bukowski, H.-T. Tseng, J.R. Gallagher, Z. Wu, E. Wegener, A.J. Kropf, B. Ravel, F.H. Ribeiro, J.G. Greeley, J.T. Miller, “Zinc Promotion for Light Alkane Dehydrogenation: Insights into Catalyst Geometric and Electronic Structure,” ACS Catal., 7, 4173–4181 (2017).[Link]
• V.J. Cybulskis, S.U. Pradhan, J.J. Lovón-Quintana, A.S. Hock, B. Hu, G, Zhang, W. N. Delgass, F.H. Ribeiro, J.T. Miller, “The Nature of the Isolated Gallium Active Center for Propane Dehydrogenation on Ga/SiO­2,” Catal. Lett. 147, 1252–1262 (2017).[Link]
• Y. Xiao and A. Varma, Kinetics of glycerol conversion to hydrocarbon fuels over Pd/H‐ZSM‐5 catalyst, AIChE Journal, 63 (2017) 5445-5451[Link]
• Y. Xiao and A. Varma, Kinetics of Guaiacol Deoxygenation using Methane over the Pt-Bi Catalyst, Reaction Chemistry & Engineering, 2 (2017) 36-43[Link]
• Z. Ma, Z. Wu, J.T. Miller, “Effect of Cu content on the bimetallic Pt-Cu catalysts for propane dehydrogenation,” Catalysis, Structure & Reactivity, 3, 43-53 (2017).[Link]
• Z. Ma, Z. Wu, J.T. Miller, “Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation,” J. of Visual Exp, http://www.jove.com/video/56040?status=a58046k (2017).[Link]
• Z. Su, Y.-R. Miao, G. Zhang, J.T. Miller, K.S. Suslick, “Bond Breakage under Pressure in a Metal Organic Framework,” Chemical Science, 8, 8004-8011 (2017).[Link]



2016 (top)



• C. Paolucci, J. R. Di Iorio, F. H. Ribeiro, R. Gounder and W. F. Schneider Catalysis Science of NOx Selective Catalytic Reduction With Ammonia Over Cu-SSZ-13 and Cu-SAPO-34, Advances in Catalysis, 59 (2016)
• J. C. Vega-Vila, J. W. Harris and R. Gounder Controlled insertion of tin atoms into zeolite framework vacancies and consequences for glucose isomerization catalysis, Journal of Catalysis, 344 (2016) 108-120
• V. J. Cybulskis, J. W. Harris, Y. Zvinevich, F. H. Ribeiro and R. Gounder A Transmission Infrared Cell Design for Temperature-Controlled Adsorption and Reactivity Studies on Heterogeneous Catalysts, Review of Scientific Instruments, 87 (2016) 103101
• Patrick Wolf, Wei-Chih Liao, Ta-Chung Ong, Maxence Valla, James W. Harris, Rajamani Gounder, William N. P. van der Graaff, Evgeny A. Pidko, Emiel J. M. Hensen, Paola Ferrini, Jan Dijkmans, Bert Sels, Ive Hermans, Christophe Copéret Identifying Sn Site Heterogeneities Prevalent Among Sn-Beta Zeolites, Helvetica Chimica Acta, (2016)
• James W. Harris, Michael J. Cordon, John R. Di Iorio, Juan C. Vega-Vila, Fabio H. Ribeiro and Rajamani Gounder, Titration and Quantification of Open and Closed Lewis Acid Sites in Sn-Beta Zeolites that Catalyze Glucose Isomerization, Journal of Catalysis, 335 (2016) 141-154
• Zhenwei Wu, Evan C. Wegener, Han-Ting Tseng, James R. Gallagher, James W. Harris, Rosa E. Diaz, Yang Ren, Fabio H. Ribeiro and Jeffrey T. Miller, Pd–In intermetallic alloy nanoparticles: highly selective ethane dehydrogenation catalysts, Catal. Sci. Technol., 6 (2016), 6965 - 6976
• Y Xiao, J Greeley, A Varma, ZJ Zhao, G Xiao An experimental and theoretical study of glycerol oxidation to 1,3-dihydroxyacetone over bimetallic Pt-Bi catalysts, AIChE Journal, (2016)
• Jeffrey Greeley Theoretical Heterogeneous Catalysis: Scaling Relationships and Computational Catalyst Design, Annual review of chemical and biomolecular engineering 7 (2016), 605-635
• Z Zeng, J Greeley Characterization of oxygenated species at water/Pt (111) interfaces from DFT energetics and XPS simulations, Nano Energy
• Christopher Paolucci, Atish A. Parekh, Ishant Khurana, John R Di Iorio, Hui Li, Jonatan D. Albarracin Caballero, Arthur Shih, Trunojoyo Anggara, W. Nicholas Delgass, Jeffrey T Miller, Fabio H Ribeiro, Rajamani Gounder, and William F. Schneider, Catalysis in a Cage: Condition-Dependent Speciation and Dynamics of Exchanged Cu Cations in SSZ-13 Zeolites, J. Am. Chem. Soc., (2016) 138 (18), pp 6028–6048
• RE Warburton, H Iddir, LA Curtiss, J Greeley Thermodynamic Stability of Low-and High-Index Spinel LiMn₂O₄ Surface Terminations, ACS applied materials & interfaces 8 (2016), 11108-11121
• Viktor J. Cybulskis, Jun Wang, Jorge H. Pazmiño, Fabio H. Ribeiro, W. Nicholas Delgass, Isotopic Transient Studies of Sodium Promotion of Pt/Al₂O₃ for the Water-Gas Shift Reaction, Journal of Catalysis, 339 (2016) 163-172
• Viktor J. Cybulskis, Fabio H. Ribeiro, Rajamani Gounder, Using a Hands-On Hydrogen Peroxide Decomposition Activity to Teach Catalysis Concepts to K-12 Students, Journal of Chemical Education, 93, 8 (2016) 1406-1410
• Viktor J. Cybulskis P.E., Andrew D. Smeltz, Yury Zvinevich, Rajamani Gounder, W. Nicholas Delgass, Fabio H. Ribeiro, Learning the Fundamentals of Kinetics and Reaction Engineering with the Catalytic Oxidation of Methane, Chemical Engineering Education, 50, 3 (2016) | Supplementary Information
• Y Ha, Z Zeng, Y Cohen, J Greeley, AA Gewirth Electrochemical Surface Stress Development during CO and NO Oxidation on Pt, The Journal of Physical Chemistry C 120 (2016), 8674-8683
• BC Bukowski, J Greeley Scaling Relationships for Molecular Adsorption and Dissociation in Lewis Acid Zeolites, The Journal of Physical Chemistry C 120 (2016), 6714-6722
• John R. Di Iorio, Rajamani Gounder, Controlling the Isolation and Pairing of Aluminum in Chabazite Zeolites Using Mixtures of Organic and Inorganic Structure-Directing Agents, Chemistry of Materials 28 (2016) 2236-2247
• D Raciti, J Kubal, C Ma, M Barclay, M Gonzalez, M Chi, J Greeley, K L More, C Wang, Pt₃Re alloy nanoparticles as electrocatalysts for the oxygen reduction reaction, Nano Energy 20 (2016), 202-211

2015 (top)



• John R. Di Iorio, Shane A. Bates, Anuj A. Verma, W. Nicholas Delgass, Fabio H. Ribeiro, Jeffrey T. Miller, Rajamani Gounder The Dynamic Nature of Brønsted Acid Sites in Cu–Zeolites During NOx Selective Catalytic Reduction: Quantification by Gas-Phase Ammonia Titration, Topics in Catalysis 58 (2015) 424-434
• John C. Degenstein, Priya Murria, Mckay Easton, Huaming Sheng, Matt Hurt, Alex R. Dow, Jinshan Gao, John J. Nash, Rakesh Agrawal, W. Nicholas Delgass, Fabio H. Ribeiro, and Hilkka I. Kenttämaa Fast Pyrolysis of ¹³C-Labeled Cellobioses: Gaining Insights into the Mechanisms of Fast Pyrolysis of Carbohydrates, J. Org Chem 80, 3 (2015) 1909-1914
• Amir Gharachorlou , Michael Donald Detwiler , Lukas Mayr , Xiang-Kui Gu , Jeffrey Greeley , Ronald G. Reifenberger , W. Nicholas Delgass , Fabio H Ribeiro , and Dmitry Y. Zemlyanov The Surface Chemistry of Trimethylaluminium on Pd(111) and Pt(111), J. Phys. Chem. C
• Karol Furman, David Baudouin, Tigran Margossian, Kaiwalya D. Sabnis, Yanran Cui, Fabio H. Ribeiro, Christophe Copéret Increased methanation activity through passivation of the silica support, J. Catal. 324 (2015) 9-13
• Maureen McCann, Mahdi Abu-Omar, Rakesh Agrawal, Joseph Bozell, Nicholas Carpita, Clint Chapple, Michael Crowley, Nicholas Delgass, Bryon Donohoe, Michael Himmel, Hilkka Kenttamaa, Lee Makowski, Richard Meilan, Nathan Mosier, Angus Murphy, Wendy Peer, Fabio Ribeiro and Melvin Tucker Tailoring Biomass for Biochemical, Chemical or Thermochemical Catalytic Conversion, The FASEB Journal 29, 1 (2015) 485.3
• Sikander H. Hakim, Canan Sener, Ana C. Alba-Rubio, Thomas M. Gostanian, Brandon J. O’Neill, Fabio H. Ribeiro, Jeffrey T. Miller, James A. Dumesic, Synthesis of supported bimetallic nanoparticles with controlled size and composition distributions for active site elucidation, J. Catal. 328 (2015) 75-90
• Trenton Parsell, Sara Yohe, John Degenstein, Tiffany Jarrell, Ian Klein, Emre Gencer, Barron Hewetson, Matt Hurt, Jeong Im Kim, Harshavardhan Choudhari, Basudeb Saha, Richard Meilan, Nathan Mosier, Fabio Ribeiro, W. Nicholas Delgass, Clint Chapple, Hilkka I. Kenttämaa, Rakesh Agrawal and Mahdi M. Abu-Omar A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass, Green Chem. 17 (2015), 1492-1499
• Shinbeom Lee and Arvind Varma Aldol condensation of n-butyraldehyde in a biphasic stirred tank reactor: Experiments and models, AIChE Journal
• Gregory S. Honda, Eric Lehmann, Daniel A. Hickman, and Arvind Varma Effects of Prewetting on Bubbly- and Pulsing-Flow Regime Transitions in Trickle-Bed Reactors, Ind. Eng. Chem. Res.
• Michael D. Detwiler , Amir Gharachorlou , Lukas Mayr , Xiang-Kui Gu , Bin Liu , Jeffrey Greeley , W. Nicholas Delgass , Fabio H Ribeiro , and Dmitry Y. Zemlyanov, Reaction of Trimethylaluminum with Water on Pt(111) and Pd(111) from 10^-5 to 10^-1 Millibar, J. Phys. Chem. C 119, 5 (2015) 2399-2411.
• Vinod Kumar Venkatakrishnan, W. Nicholas Delgass, Fabio H. Ribeiro and Rakesh Agrawal Oxygen removal from intact biomass to produce liquid fuel range hydrocarbons via fast-hydropyrolysis and vapor-phase catalytic hydrodeoxygenation, Green Chem. 17 (2015), 178-183.

2014 (top)



• A. Gharachorlou, M. D. Detwiler, A. V. Nartova, Y. Lei, J. Lu, J. W. Elam, W. N. Delgass, F. H. Ribeiro, and D. Y. Zemlyanov, Palladium Nanoparticle Formation on TiO₂(110) by Thermal Decomposition of Palladium(II) Hexafluoroacetylacetonate, ACS Appl. Mater. Interfaces 6, 16 (2014) 14702-14711.
• A. A. Verma, S. A. Bates, T. Anggara, C. Paolucci, A. A. Parekh, K. Kamasamudram, A. Yezerets, J. T. Miller, W. N. Delgass, W. F. Schneider, and F. H. Ribeiro, NO oxidation: A Probe Reaction on Cu-SSZ-13, J. Catal. 312 (2014) 179-190.
• P. J. Dietrich, F. G. Sollberger, M. C. Akatay, E. A. Stach, W. N. Delgass, J. T. Miller, F. H. Ribeiro, Structural and catalytic differences in the effect of Co and Mo as promoters for Pt-based aqueous phase reforming catalysts, Applied Catalysis B: Environmental 156-157 (2014) 236-248.
• S. A. Bates, A. A. Verma, C. Paolucci, A. A. Parekh, T. Anggara, A. Yezerets, W. F. Schneider, J. T. Miller , W. N. Delgass, F. H. Ribeiro, Identification of the active Cu site in standard selective catalytic reduction with ammonia on Cu-SSZ-13, J. Catal. 312 (2014) 87-97.
• S. A. Bates, W. N. Delgass, F. H. Ribeiro, J. T. Miller, and R. Gounder, Methods for NH₃ Titration of Brønsted Acid Sites in Cu-Zeolites that Catalyze the Selective Catalytic Reduction of NO_x with NH₃, J. Catal. 312 (2014) 26-36.
• V. K. Venkatakrishnan, J. C. Degenstein, A. D. Smeltz, W. N. Delgass, R. Agrawal, F. H. Ribeiro, High-pressure fast-pyrolysis, fast-hydropyrolysis and catalytic hydrodeoxygenation of cellulose: production of liquid fuel from biomass, Green Chem. 16 (2014) 792-802.
• M. C. Akatay, Y. Zvinevich, P. Baumann, F. H. Ribeiro, E. A. Stach, Gas mixing system for imaging of nanomaterials under dynamic environments by environmental transmission electron microscopy, Rev. Sci. instrum. 85 (2014) 033704.
• Rajamani Gounder, Hydrophobic microporous and mesoporous oxides as Brønsted and Lewis acid catalysts for biomass conversion in liquid water, Catal. Sci. Technol. 4 (2014) 2877-2886

2013 (top)


• J. H. Pazmino, C. Bai, J. T. Miller, F. H. Ribeiro, W. N. Delgass, Effects of Support on Sulfur Tolerance and Regeneration of Pt Catalysts Measured by Ethylene Hydrogenation and EXAFS, Catalysis Letters 143 (2013) 1098-1107.
• P. J. Dietrich, M. C. Akatay, F. G. Sollberger, E. A. Stach, J. T. Miller, W. N. Delgass, F. H. Ribeiro, Effect of Co Loading on the Activity and Selectivity of PtCo Aqueous Phase Reforming Catalysts, ACS Catal. 4 (2013) 480-491.
• W. S. Lee, M. C. Akatay, E. A. Stach, F. H. Ribeiro, W. N. Delgass, Enhanced reaction rate for gas-phase epoxidation of propylene using H₂ and O₂ by Cs promotion of Au/TS-1, J. Catal. 308 (2013) 98-113.
• P. J. Dietrich, T. P. Wu, A. Sumer, J. A. Dumesic, J. Jellinek, W. N. Delgass, F. H. Ribeiro, J. T. Miller, Aqueous Phase Glycerol Reforming with Pt and PtMo Bimetallic Nanoparticle Catalysts: The Role of the Mo Promoter, Top Catal. 56 (2013) 1814-1828.
• M. R. Hurt, J. C. Degenstein, P. Gawecki, D. J. Borton II, N. R. Vinueza, L. Yang, R. Agrawal, W. N. Delgass, F. H. Ribeiro, H. I. Kenttamaa, On-Line Mass Spectrometric Methods for the Determination of the Primary Products of Fast Pyrolysis of Carbohydrates and for Their Gas-Phase Manipulation, Anal. Chem. 85 (2013) 10927-10934.

2012 (top)


• M. Shekhar, J. Wang, W. S. Lee, W. D. Williams, S. M. Kim, E. A. Stach, J. T. Miller, W. N. Delgass, F. H. Ribeiro, Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al₂O₃ and TiO₂, J. Am. Chem. Soc. 124 (2012) 4700-4708.
• J. S. McEwen, T. Anggara, W. F. Schneider, V. F. Kispersky, J. T. Miller, W. N. Delgass, F. H. Ribeiro, Integrated operando X-ray absorption and DFT characterization of Cu–SSZ-13 exchange sites during the selective catalytic reduction of NO_x with NH₃, Catal. Today 184 (2012) 129-144.
• W. S. Lee, L. C. Lai, M. C. Akatay, E. A. Stach, F. H. Ribeiro, W. N. Delgass, Probing the gold active sites in Au/TS-1 for gas-phase epoxidation of propylene in the presence of hydrogen and oxygen, J. Catal. 296 (2012) 31-42.
• W. S. Lee, M. C. Akatay, E. A. Stach, F. H. Ribeiro, W. N. Delgass, Reproducible preparation of Au/TS-1 with high reaction rate for gas phase epoxidation of propylene, J. Catal. 287 (2012) 178-189.
• P. J. Dietrich, R. J. Lobo-Lapidus, T. P. Wu, A. Sumer, M. C. Akatay, B. R. Fingland, N. Guo, J. A. Dumesic, C. J. Marshall, E. A. Stach, J. Jellinek, W. N. Delgass, F. H. Ribeiro, J. T. Miller, Aqueous Phase Glycerol Reforming by PtMo Bimetallic Nano-Particle Catalyst: Product Selectivity and Structural Characterization, Top. Catal. 55 (2012) 53-69.
• J. Wang, V. F. Kispersky, W. N. Delgass, F. H. Ribeiro, Determination of the Au active site and surface active species via operando transmission FTIR and isotopic transient experiments on 2.3 wt.% Au/TiO₂ for the WGS reaction, J. Catal. 289 (2012) 171-178.
• W. D. Williams, L. Bollmann, J. T. Miller, W. N. Delgass, F. H. Ribeiro, Effect of molybdenum addition on supported platinum catalysts for the water–gas shift reaction, Appl. Catal., B. 289 (2012) 171-178.
• J. H. Pazmiño, M. Shekhar, W. D. Williams, M. C. Akatay, J. T. Miller, W. N. Delgass, F. H. Ribeiro, Metallic Pt as active sites for the water–gas shift reaction on alkali-promoted supported catalysts, J. Catal. 286 (2012) 279-286.

2011 (top)


• J. H. Pazmiño, J. T. Miller, F. H. Ribeiro, W. N. Delgass, Kinetic studies of the stability of Pt for NO oxidation: Effect of sulfur and long-term aging, J. Catal. 282 (2011) 13-24.
• S. S. Chaugule, V. F. Kispersky, J. L. Ratts, A. Yezerets, N. W. Currier, F. H. Ribeiro, W. N. Delgass, Formation and removal of Ba-carbonates or carboxylates on Pt/BaO/γ-Al₂O₃ lean NO_x traps, Appl. Catal., B. 107 (2012) 26-33.

2010 (top)


• W. D. Williams, M. Shekhar, W. S. Lee, V. Kispersky, F. H. Ribeiro, W. N. Delgass, S. M. Kim, E. A. Stach, J. T. Miller, L. F. Allard, Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis, J. Am. Chem. Soc. 132 (2010) 14018-14020.