CM Bishop, RE García, WC Carter “Effect of charge separation on the stability of large wavelength fluctuations during spinodal decomposition” Acta materialia, 51(6): 1517-1524, 2003.
Abstract
A stability analysis of phase separation of charged species by spinodal decomposition is presented. The charge effects introduce a short wave number cutoff for linear perturbations about the homogeneous, neutral solution. Phase field calculations using a semi-implicit spectral method support this conclusion. This suggests that coarsening is limited in ionic solid systems that are unstable with respect to charged-phase separation.
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