{"id":998,"date":"2026-08-01T07:33:39","date_gmt":"2026-08-01T12:33:39","guid":{"rendered":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/?p=998"},"modified":"2026-08-01T07:33:41","modified_gmt":"2026-08-01T12:33:41","slug":"s-zhou-c-shen-h-li-y-zhang-d-estrella-a-sanjuan-d-hermawan-b-tsai-j-huang-x-sheng-a-choudhury-y-chen-r-e-garcia-x-zhang-haiyan-wang-phase-boundary-assisted-flash-sinteri","status":"publish","type":"post","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/s-zhou-c-shen-h-li-y-zhang-d-estrella-a-sanjuan-d-hermawan-b-tsai-j-huang-x-sheng-a-choudhury-y-chen-r-e-garcia-x-zhang-haiyan-wang-phase-boundary-assisted-flash-sinteri\/","title":{"rendered":"S. Zhou, C. Shen, H. Li, Y. Zhang, D. Estrella, A. Sanjuan, D. Hermawan, B. Tsai, J. Huang, X. Sheng, A. Choudhury, Y. Chen, R. E. Garc\u00eda, X. Zhang, Haiyan Wang &#8220;Phase-Boundary Assisted Flash Sintering of Al2O3-TiO2 Nanocomposites.&#8221; Acta Materialia. 302:121612, 2026."},"content":{"rendered":"\n<p class=\"wp-block-paragraph\">S. Zhou, C. Shen, H. Li, Y. Zhang, D. Estrella, A. Sanjuan, D. Hermawan, B. Tsai, J. Huang, X. Sheng, A. Choudhury, Y. Chen, R. E. Garc\u00eda, X. Zhang, Haiyan Wang &#8220;<em>Phase-Boundary Assisted Flash Sintering of Al<sub>2<\/sub>O<sub>3<\/sub>-TiO<sub>2<\/sub> Nanocomposites.<\/em>&#8221; <strong>Acta Materialia.<\/strong> 302:121612, 2026. <a href=\"https:\/\/doi.org\/10.1016\/j.actamat.2025.121612\">https:\/\/doi.org\/10.1016\/j.actamat.2025.121612<\/a><\/p>\n\n\n\n<h2 class=\"wp-block-heading\">Abstract<\/h2>\n\n\n\n<p class=\"wp-block-paragraph\">Al<sub>2<\/sub>O<sub>3<\/sub>\u00a0is inherently challenging to flash sinter due to its highly insulating nature. In contrast, TiO<sub>2<\/sub>\u00a0can be flash sintered readily due to its better electrical and ionic conductivity at elevated temperatures than those of Al<sub>2<\/sub>O<sub>3<\/sub>. In this study, two-phase composites of Al<sub>2<\/sub>O<sub>3<\/sub>-TiO\u2082 with various molar ratios (i.e., 34 mol.% Al<sub>2<\/sub>O<sub>3<\/sub>\/66 mol.% TiO<sub>2<\/sub>\u00a0and 20 mol.% Al<sub>2<\/sub>O<sub>3<\/sub>\/80 mol.% TiO<sub>2<\/sub>) have been successfully processed by flash sintering and a systematic flash sintering map has been constructed to explore the relationship between electric field (ranging from 300 to 1600 V\/cm) and the flash sintering temperature in Al<sub>2<\/sub>O<sub>3<\/sub>-TiO\u2082 composites. The map clearly demonstrates that the flash sintering temperature of composites decreases with increasing electric field or higher TiO<sub>2<\/sub>\u00a0molar ratio. The potential mechanisms of phase boundary assisted flash sintering are discussed. This study confirms that the appropriate design of two-phase composites can prominently promote the flash sintering of insulating ceramic materials.<\/p>\n","protected":false},"excerpt":{"rendered":"<p class=\"post-excerpt\" class=\"post-excerpt\">S. Zhou, C. Shen, H. Li, Y. Zhang, D. Estrella, A. Sanjuan,&hellip;<\/p>\n<div class=\"link-more\"><a href=\"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/s-zhou-c-shen-h-li-y-zhang-d-estrella-a-sanjuan-d-hermawan-b-tsai-j-huang-x-sheng-a-choudhury-y-chen-r-e-garcia-x-zhang-haiyan-wang-phase-boundary-assisted-flash-sinteri\/\">Continue reading<span class=\"screen-reader-text\"> &#8220;S. Zhou, C. Shen, H. Li, Y. Zhang, D. Estrella, A. Sanjuan, D. Hermawan, B. Tsai, J. Huang, X. Sheng, A. Choudhury, Y. Chen, R. E. Garc\u00eda, X. Zhang, Haiyan Wang &#8220;Phase-Boundary Assisted Flash Sintering of Al2O3-TiO2 Nanocomposites.&#8221; Acta Materialia. 302:121612, 2026.&#8221;<\/span>&hellip;<\/a><\/div>\n<div class=\"link-more\"><a href=\"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/s-zhou-c-shen-h-li-y-zhang-d-estrella-a-sanjuan-d-hermawan-b-tsai-j-huang-x-sheng-a-choudhury-y-chen-r-e-garcia-x-zhang-haiyan-wang-phase-boundary-assisted-flash-sinteri\/\">Continue reading<span class=\"screen-reader-text\"> \"S. Zhou, C. Shen, H. Li, Y. Zhang, D. Estrella, A. Sanjuan, D. Hermawan, B. Tsai, J. Huang, X. Sheng, A. Choudhury, Y. Chen, R. E. Garc\u00eda, X. Zhang, Haiyan Wang &#8220;Phase-Boundary Assisted Flash Sintering of Al2O3-TiO2 Nanocomposites.&#8221; Acta Materialia. 302:121612, 2026.\"<\/span>&hellip;<\/a><\/div>","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"jetpack_seo_schema_type":"","_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[45],"tags":[55,84,75,10],"class_list":["post-998","post","type-post","status-publish","format-standard","hentry","category-papers","tag-fem","tag-flash-cosintering","tag-flash-sintering","tag-grain-boundaries","entry"],"jetpack_featured_media_url":"","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/peeeSR-g6","jetpack_likes_enabled":true,"jetpack-related-posts":[{"id":970,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/07\/31\/c-shen-t-niu-b-yang-j-cho-z-shang-t-sun-a-shang-r-e-garcia-h-wang-x-zhang-micromechanical-properties-and-microstructures-of-ac-and-dc-flash-sintered-alumina-materials-science-and-engi\/","url_meta":{"origin":998,"position":0},"title":"C. Shen, T Niu, B. Yang, J. Cho, Z Shang, T Sun, A Shang, R E Garc\u00eda, H Wang, X Zhang &#8220;Micromechanical properties and microstructures of AC and DC flash-sintered alumina.&#8221; Materials Science and Engineering: A 866:144631, 2023","author":"redwing","date":"07\/31\/2026","format":false,"excerpt":"C. Shen, T Niu, B. Yang, J. Cho, Z Shang, T Sun, A Shang, R E Garc\u00eda, H Wang, X Zhang \"Micromechanical properties and microstructures of AC and DC flash-sintered alumina.\" Materials Science and Engineering: A 866:144631, 2023. https:\/\/doi.org\/10.1016\/j.msea.2023.144631 Abstract Alumina\u00a0(\u03b1-Al2O3), one of the most widely used\u00a0structural ceramics\u00a0for industrial applications,\u2026","rel":"","context":"In &quot;Papers&quot;","block_context":{"text":"Papers","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/category\/papers\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1020,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/c-liu-c-shen-j-shen-b-k-tsai-y-zhang-y-chen-y-zhang-k-xu-d-paul-j-lu-h-li-z-hu-x-sheng-a-wazeer-s-zhou-r-e-garcia-x-zhang-h-wang-in-situ-studies-on-microstructural-evolution-and-the\/","url_meta":{"origin":998,"position":1},"title":"C Liu, C Shen, J Shen, B K Tsai, Y Zhang, Y Chen, Y Zhang, K Xu, D Paul, J Lu, H Li, Z Hu, X Sheng, A Wazeer, S Zhou, R E Garc\u00eda, X Zhang, H Wang &#8220;In situ Studies on Microstructural Evolution and Thermally Activated Plasticity of (Co, Cu, Mg, Ni, Zn) O High-Entropy Oxide.&#8221; Acta Materialia, 122212, 2026.","author":"redwing","date":"08\/01\/2026","format":false,"excerpt":"C Liu, C Shen, J Shen, B K Tsai, Y Zhang, Y Chen, Y Zhang, K Xu, D Paul, J Lu, H Li, Z Hu, X Sheng, A Wazeer, S Zhou, R E Garc\u00eda, X Zhang, H Wang \"In situ Studies on Microstructural Evolution and Thermally Activated Plasticity of (Co,\u2026","rel":"","context":"In &quot;Papers&quot;","block_context":{"text":"Papers","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/category\/papers\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1007,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/bo-yang-nicholas-richter-huan-li-zhongxia-shang-zihao-he-hongyi-dou-jianan-shen-r-edwin-garcia-noam-bernstein-c-stephen-hellberg-haiyan-wang-xinghang-zhang-dislocation-enabled-plasticity\/","url_meta":{"origin":998,"position":2},"title":"Bo Yang, Nicholas Richter, Huan Li, Zhongxia Shang, Zihao He, Hongyi Dou, Jianan Shen, R Edwin Garc\u00eda, Noam Bernstein, C Stephen Hellberg, Haiyan Wang, Xinghang Zhang &#8220;Dislocation-enabled plasticity in rutile TiO2\u2212x\u00a0at room temperature.&#8221; Nanoscale. 17 (35): 20338-20350, 2025.","author":"redwing","date":"08\/01\/2026","format":false,"excerpt":"Bo Yang, Nicholas Richter, Huan Li, Zhongxia Shang, Zihao He, Hongyi Dou, Jianan Shen, R Edwin Garc\u00eda, Noam Bernstein, C Stephen Hellberg, Haiyan Wang, Xinghang Zhang \"Dislocation-enabled plasticity in rutile TiO2\u2212x\u00a0at room temperature.\" Nanoscale. 17 (35): 20338-20350, 2025. https:\/\/doi.org\/10.1039\/d5nr02684a Abstract Ceramics are widely perceived as brittle. Recent research showed that\u2026","rel":"","context":"In &quot;Papers&quot;","block_context":{"text":"Papers","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/category\/papers\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1000,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/danny-hermawan-alfredo-sanjuan-benson-kunhung-tsai-jialong-huang-r-edwin-garcia-haiyan-wang-complex-oxidemetal-hybrid-metamaterials-with-integrated-magnet\/","url_meta":{"origin":998,"position":3},"title":"J. Huang, B. Zhang, D. Hermawan, A. Sanjuan, B. Kunhung Tsai, J. Huang, R. E. Garc\u0131\u0301a, H. Wang &#8220;Complex Oxide\u2010Metal Hybrid Metamaterials with Integrated Magnetic and Plasmonic Non\u2010noble Metal Nanostructures.&#8221; Advanced Functional Materials. 35:(30), 2500741, 2025.","author":"redwing","date":"08\/01\/2026","format":false,"excerpt":"Jijie Huang, Bin Zhang, Danny Hermawan, Alfredo Sanjuan, Benson Kunhung Tsai, Jialong Huang, R Edwin Garc\u0131\u0301a, Haiyan Wang \"Complex Oxide\u2010Metal Hybrid Metamaterials with Integrated Magnetic and Plasmonic Non\u2010noble Metal Nanostructures.\" Advanced Functional Materials. 35 (30), 2500741, 2025. https:\/\/doi.org\/10.1002\/adfm.202500741 Abstract Vertically aligned nanocomposite (VAN) thin films offer exceptional physical properties through\u2026","rel":"","context":"In &quot;Papers&quot;","block_context":{"text":"Papers","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/category\/papers\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1009,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2026\/08\/01\/d-hermawan-a-sanjuan-s-doran-jf-rufner-sa-pitts-lk-aagesen-re-garcia-scaling-microstructural-processes-in-the-sintering-of-ionic-ceramics-acta-materialia-121688-2025\/","url_meta":{"origin":998,"position":4},"title":"D Hermawan, A Sanjuan, S Doran, JF Rufner, SA Pitts, LK Aagesen, RE Garc\u00eda &#8220;Scaling microstructural processes in the sintering of ionic ceramics.&#8221; Acta Materialia, 121688, 2025.","author":"redwing","date":"08\/01\/2026","format":false,"excerpt":"D Hermawan, A Sanjuan, S Doran, JF Rufner, SA Pitts, LK Aagesen, RE Garc\u00eda \"Scaling microstructural processes in the sintering of ionic ceramics.\" Acta Materialia, 121688, 2025. https:\/\/doi.org\/10.1016\/j.actamat.2025.121688 Abstract A multi-scale framework, combining a multiphase field formulation and large deformation mechanics, was developed as a stepping stone to perform the\u2026","rel":"","context":"In &quot;Papers&quot;","block_context":{"text":"Papers","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/category\/papers\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":817,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2019\/10\/19\/j-li-j-cho-j-ding-h-charalambous-s-xue-h-wang-x-l-phuah-j-jian-x-wang-c-ophus-t-tsakalakos-r-e-garcia-a-k-mukherjee-n-bernstein-c-s-hellberg-h-wang-x-zhang-nanoscale\/","url_meta":{"origin":998,"position":5},"title":"J. Li, J. Cho, J. Ding, H. Charalambous, S. Xue, H. Wang, X.L. Phuah, J. Jian, X. Wang, C. Ophus, T. Tsakalakos, R.E. Garc\u00eda, A.K. Mukherjee, N. Bernstein, C.S. Hellberg, H. Wang, X. Zhang &#8220;Nanoscale stacking fault\u2013assisted room temperature plasticity in flash-sintered TiO2.&#8221; Science Advances. 5 (9): eaaw5519, 2019.","author":"redwing","date":"10\/19\/2019","format":false,"excerpt":"J. Li, J. Cho, J. Ding, H. Charalambous, S. Xue, H. Wang, X.L. Phuah, J. Jian, X. Wang, C. Ophus, T. Tsakalakos, R.E. Garc\u00eda, A.K. Mukherjee, N. Bernstein, C.S. Hellberg, H. Wang, X. Zhang \"Nanoscale stacking fault\u2013assisted room temperature plasticity in flash-sintered TiO2.\" Science Advances. 5 (9):eaaw5519, 2019;\u00a0https:\/\/advances.sciencemag.org\/content\/5\/9\/eaaw5519?intcmp=trendmd-adv abstract Ceramic\u2026","rel":"","context":"In &quot;Papers&quot;","block_context":{"text":"Papers","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/category\/papers\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts\/998","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/comments?post=998"}],"version-history":[{"count":1,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts\/998\/revisions"}],"predecessor-version":[{"id":999,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts\/998\/revisions\/999"}],"wp:attachment":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/media?parent=998"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/categories?post=998"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/tags?post=998"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}