{"id":847,"date":"2020-09-27T08:41:54","date_gmt":"2020-09-27T13:41:54","guid":{"rendered":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/?p=847"},"modified":"2020-09-27T09:00:23","modified_gmt":"2020-09-27T14:00:23","slug":"ksn-vikrant-h-wang-a-jana-h-wang-re-garcia-flash-sintering-incubation-kinetics-npj-computational-materials-61-1-8-2020","status":"publish","type":"post","link":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2020\/09\/27\/ksn-vikrant-h-wang-a-jana-h-wang-re-garcia-flash-sintering-incubation-kinetics-npj-computational-materials-61-1-8-2020\/","title":{"rendered":"KSN Vikrant, H Wang, A Jana, H Wang, RE Garc\u00eda &#8220;Flash sintering incubation kinetics&#8221; npj Computational Materials 6(1): 1-8, 2020."},"content":{"rendered":"<p>KSN Vikrant, H Wang, A Jana, H Wang, RE Garc\u00eda &#8220;<em>Flash sintering incubation kinetics.<\/em>&#8221; <strong>npj Computational Materials<\/strong> 6(1): 1-8, 2020. \u00a0<a href=\"https:\/\/doi.org\/10.1038\/s41524-020-00359-7\">https:\/\/doi.org\/10.1038\/s41524-020-00359-7<\/a><\/p>\n<h3>Abstract<\/h3>\n<p>The microstructural mechanisms leading to onset of the flash sintering are demonstrated experimentally and theoretically for Yttria Stabilized Zirconia, YSZ. Three regimes leading to flash event are identified: (1) Radiation-dominated regime, where the oven controls the heating of the sintered sample, and a small subset of particle-particle contacts and surfaces of the green body define percolative paths for the charge to flow along and across the interfaces; (2) Transition regime, where charge transport is suppressed across particle contact misorientations and deflects to surficial and small angle particle contact misorientations. As a result, internal Joule heating takes over externally-driven radiation heating. Finally, (3) Percolative regime, where the concentration of oxygen vacancies drastically increases at particle contacts, surfaces, and triple junctions, and enables charge to flow through multiple paths, generating large amounts of Joule heating, resulting in the onset of a flash event. The validated theory sets the stage to rationalize the microstructural evolution and charge transport on a ceramic green body during flash sintering.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p class=\"post-excerpt\" class=\"post-excerpt\">KSN Vikrant, H Wang, A Jana, H Wang, RE Garc\u00eda &#8220;Flash sintering&hellip;<\/p>\n<div class=\"link-more\"><a href=\"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2020\/09\/27\/ksn-vikrant-h-wang-a-jana-h-wang-re-garcia-flash-sintering-incubation-kinetics-npj-computational-materials-61-1-8-2020\/\">Continue reading<span class=\"screen-reader-text\"> &#8220;KSN Vikrant, H Wang, A Jana, H Wang, RE Garc\u00eda &#8220;Flash sintering incubation kinetics&#8221; npj Computational Materials 6(1): 1-8, 2020.&#8221;<\/span>&hellip;<\/a><\/div>\n<div class=\"link-more\"><a href=\"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2020\/09\/27\/ksn-vikrant-h-wang-a-jana-h-wang-re-garcia-flash-sintering-incubation-kinetics-npj-computational-materials-61-1-8-2020\/\">Continue reading<span class=\"screen-reader-text\"> \"KSN Vikrant, H Wang, A Jana, H Wang, RE Garc\u00eda &#8220;Flash sintering incubation kinetics&#8221; npj Computational Materials 6(1): 1-8, 2020.\"<\/span>&hellip;<\/a><\/div>","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_publicize_message":"","jetpack_is_tweetstorm":false,"jetpack_publicize_feature_enabled":true},"categories":[45],"tags":[76,6,10,14,48],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/peeeSR-dF","jetpack_likes_enabled":true,"jetpack-related-posts":[{"id":775,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2018\/10\/09\/h-wang-xl-phuah-j-li-tb-holland-ksn-vikrant-l-qiang-cs-hellberg-n-bernstein-re-garcia-a-mukherjee-x-zhang-h-wang-key-microstructural-characteristics-in-flash-sintered-3ysz-critical-for-e\/","url_meta":{"origin":847,"position":0},"title":"H Wang, XL Phuah, J Li, TB Holland, KSN Vikrant, L Qiang, CS Hellberg, N Bernstein, RE Garc\u00eda, A Mukherjee, X Zhang, H Wang. &#8220;Key microstructural characteristics in flash sintered 3YSZ critical for enhanced sintering process.&#8221; Ceramics International. 45:1251-1257, 2019.","date":"10\/09\/2018","format":false,"excerpt":"H Wang, XL Phuah, J Li, TB Holland, KSN Vikrant, L Qiang, CS Hellberg, N Bernstein, RE Garc\u00eda, A Mukherjee, X Zhang, H Wang. \"Key microstructural characteristics in flash sintered 3YSZ critical for enhanced sintering process.\" Ceramics International. 45:1251-1257, 2019. https:\/\/doi.org\/10.1016\/j.ceramint.2018.10.007 Abstract To explore the fundamental flash sintering mechanisms in\u2026","rel":"","context":"In &quot;Papers&quot;","img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":873,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2020\/10\/31\/ksn-vikrant-w-rheinheimer-re-garcia-electrochemical-drag-effect-on-grain-boundary-motion-in-ionic-ceramics-npj-computational-materials-6165-2020\/","url_meta":{"origin":847,"position":1},"title":"KSN Vikrant, W Rheinheimer, RE Garc\u00eda &#8220;Electrochemical drag effect on grain boundary motion in ionic ceramics.&#8221; npj Computational Materials. 6:165, (2020).","date":"10\/31\/2020","format":false,"excerpt":"KSN Vikrant, W Rheinheimer, RE Garc\u00eda \"Electrochemical drag effect on grain boundary motion in ionic ceramics.\" npj Computational Materials. 6:165, (2020). \u00a0https:\/\/doi.org\/10.1038\/s41524-020-00418-z Abstract The effects of drag imposed by extrinsic ionic species and point defects on the grain boundary motion of ionic polycrystalline ceramics were quantified for the generality of\u2026","rel":"","context":"In &quot;Papers&quot;","img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":854,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2020\/10\/01\/rl-grosso-ksn-vikrant-l-feng-ens-muccillo-dnf-muche-gs-jawaharram-cm-barr-am-monterrosa-rhr-castro-re-garcia-k-hattar-sj-dillon-ultrahigh-temperature-in-situ-transmission-electron-microsco\/","url_meta":{"origin":847,"position":2},"title":"RL Grosso, KSN Vikrant,  RE Garc\u00eda, K Hattar, SJ Dillon, et al. &#8220;Ultrahigh Temperature in situ Transmission Electron Microscopy based Bicrystal Coble Creep in Zirconia II: Interfacial Thermodynamics and Transport Mechanisms.&#8221;  Acta Materialia, 200:1008-1021, 2020.","date":"10\/01\/2020","format":false,"excerpt":"RL Grosso KSN Vikrant, L Feng, ENS Muccillo, DNF Muche, GS Jawaharram, CM Barr, AM Monterrosa, RHR Castro, RE Garc\u00eda, K Hattar, SJ Dillon \"Ultrahigh Temperature in situ Transmission Electron Microscopy based Bicrystal Coble Creep in Zirconia II: Interfacial Thermodynamics and Transport Mechanisms.\"\u00a0Acta Materialia, 200:1008-1021, 2020.\u00a0https:\/\/doi.org\/10.1016\/j.actamat.2020.08.070 Abstract This work uses\u2026","rel":"","context":"In &quot;Papers&quot;","img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":879,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2021\/01\/21\/k-s-n-vikrant-x-l-phuah-j-lund-han-wang-c-s-hellberg-n-bernstein-w-rheinheimer-c-m-bishop-h-wang-and-r-e-garcia-modeling-of-flash-sintering-of-ionic-ceramics-mrs-bulletin-janua\/","url_meta":{"origin":847,"position":3},"title":"K.S.N. Vikrant, X.L. Phuah, J. Lund, Han Wang, C.S. Hellberg, N. Bernstein, W. Rheinheimer, C.M. Bishop, H. Wang, and R.E. Garc\u00eda &#8220;Modeling of flash sintering of ionic ceramics.&#8221; MRS Bulletin, 46(1):67-75, 2021.","date":"01\/21\/2021","format":false,"excerpt":"K.S.N. Vikrant, X.L. Phuah, J. Lund, Han Wang, C.S. Hellberg, N. Bernstein, W. Rheinheimer, C.M. Bishop, H. Wang, and R.E. Garc\u00eda \"Modeling of flash sintering of ionic ceramics.\" MRS Bulletin, 46(1):67-75, 2021.\u00a0doi:10.1557\/s43577-020-00012-0 abstract A fundamental understanding of the influence of defects in ionic ceramics at the atomic, microstructural, and macroscopic\u2026","rel":"","context":"In &quot;Papers&quot;","img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":777,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2018\/09\/11\/sk-jha-xl-phuah-j-luo-cp-grigoropoulos-h-wang-e-garcia-b-reeja%e2%80%90jayan-the-effects-of-external-fields-in-ceramic-sintering-journal-of-the-american-ceramics-society-in-press-se\/","url_meta":{"origin":847,"position":4},"title":"SK Jha, XL Phuah, J Luo, CP Grigoropoulos, H Wang, E Garc\u00eda, B. Reeja\u2010Jayan. &#8220;The effects of external fields in ceramic sintering.&#8221; Journal of the American Ceramics Society. 102(1):5-31, 2019.","date":"09\/11\/2018","format":false,"excerpt":"SK Jha, XL Phuah, J Luo, CP Grigoropoulos, H Wang, E Garc\u00eda, B. Reeja\u2010Jayan. \"The effects of external fields in ceramic sintering.\" Journal of the American Ceramics Society. 102(1):5-31, 2019. https:\/\/doi.org\/10.1111\/jace.16061 Abstract Field\u2010assisted processing techniques can enhance the kinetics of powder synthesis, accelerate sintering processes, and drive phase transformations at\u2026","rel":"","context":"In &quot;Papers&quot;","img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":764,"url":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/2018\/05\/15\/high-temperature-deformability-of-ductile-flash-sintered-ceramics\/","url_meta":{"origin":847,"position":5},"title":"J. Cho, Q. Li, H. Wang, Z. Fan, J. Li, S. Xue, K. S. N. Vikrant, H. Wang, T. B. Holland, A. K. Mukherjee, R. E. Garc\u00eda,  X. Zhang \u201cHigh temperature deformability of ductile flash-sintered ceramics via in-situ compression.\u201d Nature Communications.  9: 2063 (2018).","date":"05\/15\/2018","format":false,"excerpt":"J. Cho, Q. Li, H. Wang, Z. Fan, J. Li, S. Xue, K. S. N. Vikrant, H. Wang, T. B. Holland, A. K. Mukherjee, R. E. Garc\u00eda, X. Zhang \u201cHigh temperature deformability of ductile flash-sintered ceramics via in-situ compression.\u201d Nature Communications. 9:2063 (2018). https:\/\/doi.org\/10.1038\/s41467-018-04333-2 Abstract Flash sintering has attracted significant\u2026","rel":"","context":"In &quot;Papers&quot;","img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts\/847"}],"collection":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/comments?post=847"}],"version-history":[{"count":1,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts\/847\/revisions"}],"predecessor-version":[{"id":848,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/posts\/847\/revisions\/848"}],"wp:attachment":[{"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/media?parent=847"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/categories?post=847"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/engineering.purdue.edu\/ComputationalMaterials\/index.php\/wp-json\/wp\/v2\/tags?post=847"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}